Improving adhesion of paint to polypropylene

A. Probably uncured tacky paint can be used. Silicone sealant can be used too.

Hope it helps and good luck!

Thanks Goran Budija, I have not tried "sticky paint" but I have had modest amounts of luck with VERY hot hotmelt glue, mixed with PP "fluff" (toy stuffing).

I have tried silicone sealant on untreated PP as well as pre-treating with acetone ⇦ this on eBay or Amazon [affil links] Warning! highly Flammable! , Xylene ⇦ this on eBay or Amazon [affil links] , ethyl acetate and others.

Have not found any way to make silicone seal to PP unfortunately. Was thinking of trying benzine as that is supposed to be unsuitable for use with PP - so presumably does SOMETHING to the outer layer.

Thanks for the thoughts, much appreciated. I am going to try bonding test pieces with an assortment of glues on top of an assortment of inks and paints. In the (perhaps unlikely) event I find anything interesting, I will share my findings.

A. Gold leaf size glue (oil based not modern water based) can be used probably but it is too expensive. That is sort of tacky oil varnish. I think that you can prepare your own tacky varnish-glue from hot sunflower oil and some beeswax ⇦ this on eBay or Amazon [affil links] and rosin...

Hope it helps and good luck!

A. You could try applying a film of primer solution - chlorinated or functionalised polyprop emulsions. In conjunction with abrasion, this can produce strong durable bonds using most common adhesives.

A. I think I've got it a great solution, but not the solution you asked for.

I use a soldering with a tip that I hammered to be shaped like a slightly rounded flat head screw driver. And I poke it threw the first layer and weld the lower to the layer below like spot welding. It works amazing at sticking corrugated PP to the top of trash cans and Buckets to keep the rain out of my roof top hydroponics and leave some overhang to shade the sides. Also putting tapered steel pip in the oven at 160 °C and pushing that through holes in the PP to make flanges and stuff.

A. Rick,

Had you asked me that question a month ago, I'd have said 'tough bananas' as I know of/knew of no adhesive that would bond well to either PP or Pe.

But the other day someone said that there's now a bonding agent for adhering fibreglass to Polypropylene ... in the plastics (chemical) fabricating field in the past, one has had to use heat fused glass fibres in order to bond FRP to the PP.

Apparently this is an adhesive ... so may I suggest that you contact your local fibreglass resin SUPPLIERS to see if there's any truth at all about this adhesive. Personally, I'd have my doubts.

By the way, natural PP, talc filled or not, will eventually U.V. degrade unless it has U.V. fillers (Carbon black, etc.) but you'd know that, I'm sure.

I wish you luck,

A. Hi Rick

Although you say you don't want to coat I have done some work on water borne primers for automotive that may fit your need. These coatings were for aftermarket polypro parts. The project never completed due to the issues brought on by consumers vs insurance companies; however, a factory applied type primer finish may be viable.

Good Luck

A. Rick,

Further to my previous reply, may I make a comment?

Why in the hell are you using PP?

Why don't you use PVC? Most window mfgrs use PVC. It is much More resistant. It can be painted more easily. It doesn't have such a high coef. of thermal expansion. Parts' quality would, I think, be much more easily controlled.

Lastly, this may cost less to do apart from having less painting hassles.

The only advantages that PP has over PVC is a somewhat better resistance to temperature and to some solvents like acetone. C'est tout!

I should have mentioned this before. Sorry.

Cheers !

! Hot melt PP based adhesives, while not considered to be "structural", will bond to untreated PP. YH America or Aica could help you. If anybody has found anything else to bond to it without surface treatment, I'd love to know about it.

PP is a straight chain simple hydrocarbon, and is eaten up by UV. Vinyl is much better, in part due to its structure. Why is PP being pushed in applications where it really doesn't fit (i.e., outdoor, painting, bonding)?

Because it's CHEAP. This is what happens when the accountants take control of material selection. Let me know the name of the windows, so I can avoid them.

Why not try to bond to Teflon, while we're at it? Oh wait, it ain't CHEAP.

Thanks guys for making this understandable to the layman. My tale. I purchased an 04 Bayliner 285 and had the letters stenciled on the transom rear facing door of this boat as the Coast Guard recommends (3 inch letters etc). The problem? The lettering didn't stick as was promised by the technician / installer. We were all perplexed, confused and generally walking around with wrinkled brows. So I took the piece (30" X 18" porous surface) to a local plastics Guru. He came out of his lab smiling saying this was polypropylene.

Q. Now, the question is simple...do I resurface so the stencil will adhere better or do I determine a paint that will securely adhere to the original porous surface.

Appreciate your response!

A. I found this thread while searching for a similar need for allowing acrylic (waterborne artist) paints to adhere to PP.

"Although I am searching for a clear product to act as a primer/tie coat, I would suggest the easiest solution for this person is to buy some of the Krylon Fusion ⇦ this on eBay or Amazon [affil links] spray paint, and make a masking tape stencil for the lettering onto the boat hull. Although my company is in no way affiliated with Krylon, they make some pretty strong claims that Fusion will adhere to normally hard to coat plastics."

A. Adhesion promoters are commonly used in the automotive aftermarket for painting polypropylene and thermoplastic polyolefins, among other plastics. A light or mist coat of Bulldog adhesion promoter ⇦ this on eBay or Amazon [affil links] applied before the top coat provides excellent adhesion. It can even be mixed in some solvent based paint systems.

A. I believe that a product called BONDiT A-43 will satisfy your needs regarding a primer for painting polypropylene.

A. OK, on the issue of painting polypropylene. YES IT CAN BE DONE! The bumpers on virtually EVERY car out there are made of Polypropylene or a blend thereof.

Painting it is as easy as painting everything else if you know what to use. First, clean the RAW plastic with a product called Super Clean Plastic Cleaner (part number 1000-A)

This will remove any waxes, residues, mold release agents, etc. Then spray a product called Bumper and Cladding Coat Adhesion Primer

on the plastic...

There is no need to scuff or sand the plastic.

Use a NON-Catalyzed paint to color it however you like. If you want to use a paint with isocyanates, you need to have a dry non-isocyanate containing paint in between...otherwise the adhesion will go out the window in a big way.

A. First you heat the piece with a benzene torch hot but not too hot. Before it cools wipe down with denatured alcohol wipes. Just pouring denatured alcohol on a rag will not work. Then prime with catalyzed urethane primer. Test it for yourself.

A. Lots of things don't work on PP. Complicating the issue is that it can sometimes have mold release agents on it as well. Here's the process that will get paint to stick and stay (though it can be worn off it will not flake or fall off without wear).

1) Clean the thing being painted
2) Clean the thing being painted with Transtar 1004 Prep wash. This is phosphoric acid and you might be able to just use that but I don't know for sure and I don't know the concentration. Clean everywhere and everything you're going to paint. No cleaning = no nice looking paint sticking.
3) Prime with either 3M 05907 Polyolefin adhesion promoter or Transtar 1023 TPO Adhesion promoter. I've tested these two and both work. Neither seems better than the other but they are both $30 for a single spray can (ouch, but no one said it would be cheap). Again prime everywhere and everything you want to paint. This stuff apparently slightly changes the chemical makeup of the surface of the PP to make the paint stick. I had to go through research papers, a company in Japan and a very surprised chemical engineer who has probably never before gotten a call directly from a customer.
4) Paint. I have used Rustoleum Appliance Epoxy. Krylon Fusion might work, but I have found it lacking in other plastic situations. Their standard interior/exterior works better on ABS than Fusion.
5) Let the thing dry for at least three days.

A. Have you ever heard anything about atmospheric plasma systems? It could be useful for painting PP materials.
There is only initial investment costs, not continuous costs.

Hope this info can help you.
Take care.

Concerning the above problem, you would get more useful answer from under described information.

Notice the term : AMAPPA
AMAPPA means PP-g-MAH-Polyetheramine (MAH:Maleic Anhydrate)

There are two type of AMAPPA
1. Resin Type : Mixable with PP Resin
2. Emulsion Type : Like Primer(waterborne and solventborne)

A. Polyethylene and polypropylene are called polyolefins. The surface of this material is nothing other then hydrogen atoms. Basically there is nothing for the paint to associate with. By the way I am a paint chemist. The surface tension is low. Low surface tension makes the Teflon fry pan non stick. If the paint can not wet the material well it will not adhere. There are ways to paint this however. Everyone is tempted to take short cuts but they will fail. A Poly Olefin Primer may be applied. This is made of a Chlorinated Polyolefin produced by Eastman Kodak. It is only soluble in Toluene or Xylene . It is best applied at low solids 2-3% or 97% solvent. The applied film is very thin and the subsequent coating is put over this, The CPO sticks to the PP and the paint sticks to the CPO primer. Other ways are to flame treat or plasma treat. What this produces chemically , are carbonyl, hydroxyl, or carboxyl molecules on the surface of the treated material. These groups give the paint something it can sink its teeth into. These are methods that do work. What happen every time is the Mfg. produces a part and then decides to paint it. The molding material is the critical piece to the painting ? Simply said PE and PP are very difficult to adhere to. All due to the inert surface.

A. As well as the paint you use, the application technique (especially when using stencils) can cause the paint to peel.
The most common cause is down to applying the first coat of paint too thick or maybe not timing the re-coats correctly.
As different paints require different techniques, it pays to read and understand the instructions

A. To get paint to better adhere to poly.

1. Clean plastic with cleaner, e.g., Zep Degreaser ⇦[this on Amazon affil links]
2. Scour plastic with 000 steel wool ⇦ this on eBay or Amazon [affil links]
3. Clean plastic with cleaner e.g. Zep Degreaser.
4. Gently heat plastic with propane torch ⇦ this on eBay or Amazon [affil links] until surface looks oily.
5. Clean with alcohol until surface is free of oil.
6. Paint with plastic primer.

A. Hi, I'm Amanda S. From Kentucky and I happened across this conversation in pursuit of some answers of my own. I've been dabbling in adhesives in many of my art projects. I'm not sure it this will work for a base but it's worth a shot, and it's an inexpensive experiment that may also be beneficial to your cheap skate superiors: Make a stencil for the lettering with tape or whatever you use, then fill the stencil with baking soda [in bulk on eBay or Amazon [affil links] and pour liquid super glue on top of the baking soda (try to stay inside the stencil). This stuff dries instantly and can be sanded down for a smoother surface. Paint the letters after a quick sanding, and good luck! Hope it works out for you.