Seeking Iridescent Paint or Powder Coating

A. Hi Kyle. Sorry if I misled you, but I think you misinterpreted what I was trying to say :-(

I doubt that there is likelihood of being able to anodize a zinc or zinc-nickel coating in the way you are probably envisioning. While anodizing titanium can coat it with a partial wavelength thickness of transparent oxide, which can generate the interference pattern for a rainbow effect, I was trying to say that chromate coatings on zinc plating and zinc-nickel plating have some capacity to generate iridescence, as do thin coatings of oil, flame coloring, etc.

There is a video further down on this thread purporting to illustrate a rainbow coating that can be achieved by simple dipping in a proprietary chemical. Anodizing titanium or a titanium coating probably remains the most generic, robust and proven pathway to rainbow coatings.

Luck & Regards,

A. Hi Glenn. We added your inquiry to a thread which discusses rainbow coatings, and as you'll read here, it's not titanium per se which explains them, it is any very thin (partial wavelength) transparent or highly translucent coating where some of the light striking an object bounces off the outermost surface, and some penetrates the clear coating and bounces off the object (or underside of the clear coating). Splitting the light this way, with half or so of it taking the short path (bouncing off the outside of the coating) and the rest taking the longer path (bouncing off the inside of the coating) puts the two portions of the reflected light out of sync with each other, amplifying some wavelengths and suppressing others.

Titanium oxide coatings are probably the best and most robust rainbow finish, but not the only one. They can be done with oxide coatings on stainless steel, burnt oils (heat coloring), oxide coatings on aluminum, and -- it would seem from a video below -- even with proprietary dip coatings.

Luck & Regards,

A. Dear Jon, Without giving you an exact supplier name, I can tell you that if you call a number of powder suppliers you will find that one in particular has a niche for this type of product. Remember that powder suppliers each seem to have their own niche for a property of powder I.E. wrinkle, transluscents, clears, textures, veins, etc.

A. There are several manufacturers of the powder you seek, Valspar, PPG One Source, Tiger Drylac to mention a few. Look under the suppliers section of finishing.com for companies that support this web site and you may find additional companies that also can assist you. Good Luck.

A. Dear Mert,

One good way to achieve an iridescent look would be to topcoat with a clear lacquer and put lots of thinner in the mix. This will cause the rainbow effect you are looking.

adv.
If you are looking for a metallic coating to achieve this effect, you can take a look at our website, then contact us via email or call us. Hope this helps,

Sincerely,

A. There is a type of paint called Chroma-lusion (Dupont), Kameleon and others (PPG, Sherwin Williams). It changes through five different colors and they have about 60 different combinations. cost is about $40/2 oz. Any automotive paint supplier should carry it. Has to be seen in person to get the full effect.

One manufacturer supplies the plates to all the paint makers.

House of Kolor paints

on eBay or

Amazon

(affil links)

A. Try House of Kolor.

I'm not sure what you mean by iridescent but these people will have it. Good Luck, --Tony

A. There is a company which specializes in very colorful car paint. It has a line of sprays in all sorts of dichroic colors. A sample kit is around $100. Their name is Alsa Corp.

A. By coincidence, I was thumbing through Good Housekeeping today and there was an ad from TruValue Hardware Stores for paint supplies describing how to get some of the weird effects like skyscapes with clouds, flocked finishes, etc.

They showed one that was sort of iridescent, I guess. It involved two layers of paint, close in shade. The slightly paler color was put on first, then the second coat was an enamel in a very slightly darker shade and put on with a rag so that the background color showed through to varying degrees, giving a luminous look. The top coat was actually comprised of one part enamel to two parts of what they called 'glaze' but I don't know exactly what 'glaze' is--perhaps an enamel with no pigment?--but hopefully TruValue will.

A. You have to first paint the wall a flat color of your choice, you can finish over it with a glittering clear acrylic paint, you can find the sample of what you like in a craft store near you (like Michaels) and take it to a hardware store (like Home Depot) to find the match. If you like you can also sponge a darker glaze over it, if you have Home Depot in your area check for accent and texture paints, they have a bunch of brochures and guides for all sorts of beautiful artistic finishes.

A. I can't speak for a given manufacturer about how their paint works, C-C, but Jake has told you how it is generally achieved (very thin layer of clear coat lacquer), and I can point you to info about the general principle of iridescence -- which applies to oil sheen on water, the rainbow colors reflected off a CD or DVD, the funny pink-green-purple colors you see in some new automotive headlights, and the many other cases where you see rainbow like reflections.

Iridescence is also seen in carnival glass. Good luck.

A. They add pearl dust to paint to get the effect.

A. Another manufacturer for special effect paints, especially dichroic effect is Stardust Colors SAS, St. Laurent, France, stardustcolors.co.uk
They propose a few dichroic effects:
- prismatic (create a rainbow reflection), available in particles size from 200µ to 12µm (that is the size of a blood cell)
- chameleon paints (creating color changing effects - from 2 to 5 colors) depending on the angle of view

A. Hi Wendy. The general "oil slick" look is the result, as we have mentioned, of a very thin translucent coating such that some of the incident light reflects from the outside of the coating and some of it passes through the coating and reflects from the base, and the two portions of the reflected light interfere, canceling out some wavelengths. Where the coating is thicker it's one color, and where it's thinner it's another.

Carnival Glass

But trying to determine exactly how it was done is not always easy. In the case of titanium it's done by electrically building an anodized layer of varying thickness; in the case of pretty copper items it's done by applying oil and torch drying it to different thicknesses, in the case of carnival glass it's done with a thin metallic salt bath before final firing.

Although I have no actual knowledge of the method used for your piece, if it's pottery/plaster I doubt that either anodizing or torching would be employed. That leaves me thinking it was probably made the way "carnival glass" is made. You can probably google quite a bit about that. Good luck.

Regards,

A. Hello Jerry McDonald!

I don't know whether you ever found an answer for your question about iridizing glass.

Firstly, just in case:
-- Iridescence is caused by the refraction of light through "micro-prisms" (my word) formed by structural unevenness of the surface of a material that cause the light to bounce around in a way that breaks white light into its visible constituent wavelengths.
-- Attempts to reproduce that effect seek to duplicate those "micro-prisms".
-- TRUE iridized glass is made by coating the still-hot glass with metal salts, and then giving the glass a final firing to create the refraction, i.e. the iridizing effect, by disturbing the surface enough for "micro-prisms" to form. The crystalline nature of the micro-structures is critical to the extent and quality of the refraction.
-- To be honest, as a glass artist, it seems to me that "painting" the glass parts of antiques would be analogous to dipping a coin from Ancient Greece in chemical tarnish-remover bought at the local "mega-mart".

If your item uses flat pieces of glass, it'd be best to have them replaced, by an artisan, using actual iridized glass, which comes in 2mm-thick and 3mm-thick sheets; there might be 1-mm sheets?, but I'd have to check on that to be sure. If the objects to be restored have rounded glass parts, look into the possibility of having the glass parts made to order by a Glass Artist who can use Fuming to achieve a true iridized finish.

But, if this is for your own decor, and you'd be satisfied with a painted-on coating:

Look for iridescent medium/paints in good Artist's Supply shops and in Stained-Glass Supply shops, either in your area or on-line, as you prefer. The latter would probably be a better resource.

There are some articles online that describe using a applying "glaze" (thinned clearcoat), letting it become semi-dry, and then using a trowel/large palette knife to apply additional thinned topcoat in a "hatchmark" type of pattern, so that the resulting surface-structure bounces light around is a way similar to those "micro-prisms". I'm highly skeptical and would have to see it to believe it - I think the effect would be more silk-like, rather than "iridescent".

I also did see something about using lacquer. I assume that the "highly thinned lacquer" is supposed to dry with enough surface unevenness to create the iridescent effect, but *IF* it works at all, I think it'd be more by accident than by design. This *might* work with optical acrylic, but actual *natural* lacquer (i.e., the stuff made by the Laq beetle, harvested, and re-suspended in ethanol), well, I've worked with that, and I don't really believe it has much potential for iridescence, even though it *can* be smoothed to give wood a nearly-glass-like finish.

I think it would refer specifically to Nitrocellulose Lacquer, which is the glass-like finish seen on some musical instruments and antique furniture. You could try a very light "sputtering" spray of clear coating to only add a small number of tiny droplets at a time in layer after layer after layer, allowing each layer to dry in between. Note that word "nitrocellulose" - yes, it's flammable and requires care, AND a still and *very clean* environment. And that many layers takes a loooooong time. Agaiin, I remain skeptical and would have to see it to believe it.

I also saw some things on-line called "iridescent topcoat", "iridescent clear-coat", and "iridescent medium". If you're not going to have the glass parts replaced, look up those and similar terms.

A. Thanks Kris. Lots of good info in your posting. However, I don't think 'micro prisms' is quite the clearest explanation. Rather when you have a transparent/ clear coating on a reflective object, whether it's an organic coating or a transparent oxide like titanium metal can acquire, a portion of the light landing on it reflects off the outside of the clear coating, and a portion of it travels a bit further and reflects off the surface of the object under the clearcoat. If the coating is very thin (partial wavelength thickness), the two reflected streams of light are out of phase with each other because one traveled further -- and the two halves of the light "interfere" strengthening the greens and cancelling the reds, or strengthening the red and cancelling the greens, etc.

In the case of titanium, many different very consistent colors are obtainable by varying the anodizing voltage, which builds this transparent oxide film to different thicknesses.

(Courtesy of Russamer Lab [a finishing.com supporting advertiser])

But if you do something that results in a randomly varying film thickness (but still partial wavelength) you get rainbows like an oil slick on a mud puddle.

Luck & Regards,

A. Hi Jay. I can't speak for the manufacturer, but I think that "Neo-chrome" is their trade name for their chrome-look paint, rather than their iridescent process. Chrome look paint is available from a half dozen different suppliers, and involves a base coat of paint, followed by the reflective layer which may be either two-component silvering (silver nitrate plus an oxidizing agent) as is used in making mirrors, or tiny aluminum flakes, followed by a final clear coat. But optimizing the formulations of these three layers is the result of a lot of research & development.

The iridescent coating is some sort of clear coat, but rainbow coatings are also available from many vendors offering different technologies. I don't know whether this clearcoat is organic, or silicate, or zirconium or what. But the principal is that very thin clear coatings of varying thickness will cause a rainbow effect as light bouncing off the top of the clear coating interferes with the light reflected off the substrate. We cannot post actual formulations of this clearcoat anyway, except references to published information, as we can't know he legitimacy of a poster's knowledge and must be careful to avoid crowdsourcing industrial espionage.

Regards,

A. Hello Jay Chuah!

I did some rummaging around on the 'net. For automotive applications, I did find "car wrap" called "iridescent chrome film" that comes in several colors - $400 USD for a 5' x 60' roll. It looks like the laser-etched wrapping paper and similar refractive items, so I assume it's a laser-etched plastic film.

Otherwise, I'm commenting from an "artsy" person's perspective, not a technical one, so I don't know whether the following will help; but at the very least, there might be some ideas for searches, so here goes:

The three methods I know of for creating iridescence are [1] vacuum vapor deposition of a very thin layer of heated metal, [2] use of some form of interference pigment, and [3] finely-etching a material's surface.

None is a plating technique, as I understand the term.

(At the very end, I add a fourth method, because I just found out about it a little while ago!)

The proverbial rub with interference pigment is that it usually only involves two, or at most three, color-shifts. For example, green to violet, or blue to red. Not the full 'rainbow'. But its advantages are that it's available, it's fairly cheap, and especially, it's easy to use since it only needs to be mixed into a clear medium - it's even used in nail polish! You can buy interference pigments online.

Some potentially-useful information links for vapor deposition:
https://www.youtube.com/watch?v=-59VAnvAGLI (a 'video', more like animated flashcards, showing the basics of the vapor deposition process)
https://www.cloudynights.com/topic/615319-vapor-deposition-chamber-anyone-want-to-try-doing-a-diy-on-one/

Re: etching, you might enjoy some of these:
https://gizmodo.com/scientists-create-beautiful-iridescent-material-that-co-1825115747
From what I could find, the iridescence of truly-antique glass is due to physical etching by fine particles. I looked around for info on how to do this on purpose, but had no success - at least, not yet. I did see one example of acid-etching ceramic glaze to get a somewhat-iridescent effect. And, of course, laser-etching was mentioned at the beginning.

[4] controlled chemical oxidation to create an iridescent patina on metal - this appears to be via oxidation, rather than via chemical etching:
https://www.ganoksin.com/article/iridescent-patina-recipe/
I have no idea whether this would work on chrome, though.

Best of luck with finding what you need :)

Nice exposition, Kris!
Here I thought it was always a clear coating (whether organic or a transparent metal oxide), but that's actually only one of several ways iridescence can be achieved. Thanks!

Regards,

A. Apologies for the 6-month-late response sir, this type of iridescent coating is achieved by physical vapor deposition (PVD) of a thin film of titanium oxide or other materials onto the metal substrate. As to the setup costs or equipment, I recommend looking online for PVD setups and so on.

A. Although PVD applied titanium coatings can create this look, and are probably the most robust and wear-resistant approach, the general look can be achieved with dip coatings as we see on this page. Further, iridescent yellow chromates can produce at least a bit of this look on zinc plating, with even more purples and reds evident on zinc-nickel alloy plating. I'd bet that if a chromate conversion coating supplier put their mind to it, and a decorative applicator worked on it on individual pieces rather than bulk processing, that a very close imitation on zinc-nickel plating would be possible :-)

Luck & Regards,

A. Hi Shustine. It's readily available on the clear eye shields of motorcycle helmets, so I'd have to say yes.

Luck & Regards,