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Producing functional acid copper electroplating solution from vinegar

December 13, 2013

Q. Hello,

I'm a French hobbyist who just got started with electroplating, and am attempting to produce a functional plating solution from vinegar ⇦in bulk on eBay or Amazon [affil links] , which has 14% acetic acid , or with a more concentrated solution ⇦this on eBay or Amazon [affil links] , easily found at the chemist's.
The sooty deposit is probably the result of a combination of factors - low acidity, unstable concentration of ions, and too high a current for the ion concentration. Mark, what you say about very low currents not being enough to dissolve ions in the solution because of the lack of chlorine might explain another of my observations - that for a given experiment, the start current (i.e., what I get with a reference voltage), is always lower than in the previous experiment. It seems to indicate the solution cannot replenish itself properly.
I'll continue experimenting -- once again, as a hobbyist, I'm not after industrial quality, and it's much easier to deal with everyday products than to manipulate sulfuric acid [affil links] when you haven't got a proper workshop to start with :)
I'll keep you posted on the next experiments.
Thanks again for your help and explanations, and since we're almost there, Happy New Year!
Cheers,
J

Jeremie Marronier
- Paris, France