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Sound technical content, curated with aloha by
Ted Mooney, P.E. RET
Pine Beach, NJ
finishing.com -- The Home Page of the Finishing Industry


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Dullness problem on nickel plating




encountered dullness of nickel plating at high current density areas , e.g., around the center hole of a flat surface but the surface has bright nickel appearance. since we are keen on aesthetics, we cannot run with this condition.

Earlier we did dummy plating on the bath to remove metallic contamination such as Zinc and copper. Now, had stabilized process parameters such as boric acid, nickel content, nickel chloride, pH, temperature. Also did addition of additives and brightener as per TDS but we are still experiencing the same dilemma.

please advise on what else to check. thanks.

Jocelyn Panaguiton
process engineer - Philippines
February 28, 2011


Is around the center hole a high current density area? maybe a photo will help.

Daniel Hernandez
- Bucaramanga Santander Colombia
March 2, 2011



First of all, I'm assuming we are talking about nickel sulfamate plating.

1. Is it possible you have iron contamination? If so, raising the pH above 5.5 and treating with hydrogen peroxide will cause the iron to precipitate out.

2. Is this a rinsing issue? If the pretreatment is not getting rinsed thoroughly, is it possible that it is bleeding out in solution?

3. Exactly what current density are you plating at?

Jim Schwartzmyer
- North Tonawanda, New York
First of two simultaneous responses -- March 2, 2011



May be you will have to clearly mention the parameters you followed while dummying and the operating conditions.Dullness around the center hole - is it not Low current density area!

t k mohan
T.K. Mohan
plating process supplier - Mumbai, India
Second of two simultaneous responses -- March 2, 2011



Hi,

From the information given by you it seems the center hole is a high current density area and your problem may get reduced if you can divert some part of the current away from the center, by using appropriate auxiliary anodes. Also, reducing the current density may help serve your purpose.

All the best.

VIJAY KUMAR
- Gujarat, India
First of two simultaneous responses -- March 3, 2011



Hi,

check the filtrations, add some carbon and keishelkar powder fine media powder for fine filtrations or if you have the cartridge filter then filter the solution with new cartridges, May be the organic impurities are creating problems for you.

praveen kumar
Praveen Kumar
plating process supplier
Mumbai, India

Second of two simultaneous responses -- March 7, 2011



For illustration purposes, please see attached pictures of our materials being plated. I also include picture of cloudy sample. please comment..

56852-1


56852-2


56852-3

Jocelyn Panaguiton
- Philippines
March 7, 2011




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