Sound technical content, curated with aloha by
Ted Mooney, P.E. RET
Pine Beach, NJ
The authoritative public forum
for Metal Finishing since 1989
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Gold nickel adhesion problems
We have a Citrate based bath. The PH is on the high side never low. To maintain the bath citric acid ⇦this on eBay or Amazon [affil links] is added daily keeping the PH from 3.8 to 4.2. The bath may be saturated or possibly there is an organic contamination. Any response or suggestion would be appreciated.
Colleen L Khalifa- LA, California, USA
2007
The adhesion problem is probably related more to the condition of the nickel surface more than the capability of the gold plating bath. Are these parts freshly nickel plated without only a delay of under a minute before gold plating? If it's "old" nickel plating it must be activated, probably with a Wood's nickel strike.
Ted Mooney, P.E.
Striving to live Aloha
finishing.com - Pine Beach, New Jersey
2007
2007
Colleen,
In acid gold (citrate) formulations, there are buffer salts that have to be added occasionally to the bath to buffer the ph. You do lose some of this chemical to dragout so it has to be replenished. The baumé has to be below the max limit when you add the buffer salts, however. If you don't have a lab analysis procedure, your gold supplier should be able to provide one for you.
Like Ted said, the ph of the gold bath has little to do with adhesion problems. At a higher ph you would plate a little faster, and if it is a hardened gold you will also plate out a slightly higher gold purity - with the higher ph. Good Luck!
Process Engineer - Syracuse, New York
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