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Bath Analysis - AMS 2486 Fluoride-Phosphate

Q. Looking for methods to analyze for the baths constituents in the Fluoride-Phosphate Conversion Bath specified in AMS2486. Bath Constituents/Control -

1) trisodium phosphate ⇦ this on eBay or Amazon [affil links] (Na3PO4-12H20) 6.5 to 6.9 oz/gal
2) potassium fluoride ⇦ this on Amazon [affil links] (KF-2H20) 2.3 to 3.2 oz/gal
3) Hydrofluoric Acid (49% HF) 2.6 to 4.4 fl oz/gal

Any suggested methods for analysis is appreciated. Thank you.

Don Matthews
surface finishing - Holyoke, Massachusetts
2006

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2007

A. Don-
From an analytical point of view, this bath is more complicated than most. In order to be relatively brief, all I can do is give you a hint at what needs to be done which assumes that you are a chemist and have access to some standard metal finishing analytical reference materials. For phosphate (TSP), work out a colorimetric procedure similar method 39.02 in Aubrey Knowles' Colorimetric Analysis of Metal Finishing & Metal Working Solutions & Effluents ⇦[this on Amazon affil links]. For hydrofluoric acid, you can titrate the H+ with standard NaOH to a phenolphthalein ⇦ this on eBay & Amazon [affil links] endpoint, but that only determines part of the HF concentration since some of the HF has been neutralized by the TSP. You will need to account for the HF that was neutralized by TSP in order to get your total HF. This will require quite a bit of number crunching to express your final result in % of 48 wt% HF. For KF, you need to run total fluoride by any number of methods (search on this site) and do the math to subtract the result from the fluoride due to HF. As you can see, there is plenty of room for error as a bad result in one determination will also yield a bad result in another. Because of this, my best advice is to rely heavily on the physical properties of the coating rather than on the chemical analysis of the solution. Good Luck.

Jon Barrows, MSF, EHSSC
GOAD Company

Independence, Missouri

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Analysis Methods for Phosphate Fluoride conversion coatings

Q. Does anyone have any analysis methods to control these baths?

Greg Payne
- Belfast Northern Ireland
April 1, 2018