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ted_yosem
Sound technical content, curated with aloha by
Ted Mooney, P.E. RET
Pine Beach, NJ
finishing.com -- The Home Page of the Finishing Industry


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Iridite 14-2 dry shelf life




I have access to some very cheap Iridite. The only problem is that it's past the due date. There are 3 separate batches with the following expiration dates: 6/2003, 9/2005, and 3/2006. I am asking about what humidity and temperature this has been stored at. And I am contacting Macdermid about this. Does anybody have any experience with this? I will be using it to immersion treat 6061-t6 aluminum.

Dan Morehouse
- Bellingham, Washington
2006



First of three simultaneous responses -- 2006

Do not worry about the shelf life of 14-2. Recently in San Juan my product was tied up in Customs, we went across town and borrowed some 14-2 from a container that was 5 years old. It was as hard as a rock. It worked perfectly.

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
probertbanner



Second of three simultaneous responses --

Dan

The only way to be sure if it is any good is to process and test some coupons for your application. If you buy it and it does not perform, you're now stuck with disposal costs as well. There is a shelf life for a reason.

Willie Alexander
- Colorado Springs, Colorado
2006



Third of three simultaneous responses --

It kept dry, not clumped or caked up, it's as good as new...however...if you're doing military or other specification work, you may not be permitted to use out-of-date chemicals.

jeffrey holmes
Jeffrey Holmes, CEF
Spartanburg, South Carolina
2006



Am I missing the obvious question in all this banter? What makes an inorganic salt that's in its origi nal container bad? Has it outgassed? Has the hex chrome miraculously been reduced to trivalent? Are there magic bugs that eat up the "goodies" in the 14-2 that make it special? For the most part, chemicals we use in our industry, particularly the dry ones, don't degrade over time unless they pick up moisture from the air, get contaminated, etc. I get shelf life control for paints and epoxies and the likes, but putting shelf lives on inorganic chemicals is bad for the environment and the wallet. If it was the final case and I was being asked "deal or no deal", I'd take the deal!

milt stevenson jr.
Milt Stevenson, Jr.
Syracuse, New York
2006



2006

Milt, you seem to contradict your response in letter #42248.
A product past its expiration date cannot be used for work certified to specifications, which is why a defense contractor is making it available. Macdermid limits the shelf life of Iridite 14-2 for reasons of which we are unaware. Perhaps in a worst case scenario, a certain amount of absorbed moisture creates a reaction among ingredients, maybe involving a non-disclosed additive?

Ken Vlach [deceased]
- Goleta, California

contributor of the year Finishing.com honored Ken for his countless carefully researched responses. He passed away May 14, 2015.
Rest in peace, Ken. Thank you for your hard work which the finishing world, and we at finishing.com, continue to benefit from.




Expanding on my first answer above, I did 10 years with Allied-Kelite where 14-2 originated. The work processed above with the 5 year old 14-2 DID pass 168 hours 5% ASTM spec salt spray ! Milt is right, as usual.

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
probertbanner
2006



My understanding of quality systems, such as NADCAP, is that one would be unable to use out of shelf life materials period. It makes no difference if they are perfectly good, less expensive, and/or would create an environmental hazard. If you are not governed by one of these systems and do not have to certify the process to a specification requiring controlled shelf life materials, it sound like a good deal to me.

Chris Jurey, Past-President IHAA
Luke Engineering & Mfg. Co. Inc.
supporting advertiser
Wadsworth, Ohio
luke banner
2006




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