Summary for bluish green discoloration Discussion
Bluish green discoloration of nickel plated aluminum is reported on a pump chamber used in a laser resonator after severe testing: 65°C water exposure and broad-band flashlamp cycling at 2.0 kJ for 5.05 million flashes. The thread excerpt only includes the question from Robert H. Probert of Garner, North Carolina, and does not show any replies or diagnosis. As a result, no cause or remedy is given in the source text; the page mainly documents the observed color change under high-heat, high-flash conditions and leaves the explanation open.
Q. A have been testing a nickel plated alumimum pump chamber (for ia laser resonator) with the following parameters:
1) H20 temp=65degree C
2) exposed to broad band flashlamp @ 2.0K joules for 5.05 million flashes
The result is a bluish-green discoloration of nickel plated Alumumim.
Is this a standard type of corosive effect.
Addison Zukeran
Cynosure – Chelmsford, Massachusetts
2004
A. Since there are still no responses; A remote possibility is a cyano-bacteria or an algae. Please let us know what you find.
Tom Gallant
– Long Beach, California, USA
2004
A. After another look at your photo, I see tubing fittings. If you are using Copper tubing in the fluid circuit the blue-green could be electrolytically deposited Copper.
Tom Gallant
– Long Beach, California, USA
2004
A. I have seen similar discolorations in my work with nickel catalyst dispersed on an alumina substrate. The blue / green color you see is due to the oxidation of the nickel and its bonding with the aluminum.
Nick Def
– Portland, Oregon, USA
December 12, 2008
Q. Large Aluminum Casting with Nickel Plating.
Problem: water on casting leaving discoloration (staining). Tried wiping off water, only to find the dried area has a white stain or even a blue-ish stain.
Did several spills of water on the casting; with time cycle the water stayed on the Aluminum casting each time. In some cases the water evaporated, leaving this staining effect. Staining by this water is causing the problem.
The staining is a cosmetic issue at this time, not certain if the nickel plating is being compromised. Also tried tap water and DI water: same problem.
Any help would be appreciated.
Tom Schmitt
– Wilton, Connecticut, USA
June 11, 2013
A. The first thing to mind is that the nickel solution is in the pores of the coarse casting and the water keeps leaching it out. Try up/down/up/down. in/out/in/out, hot/cold/hot/cold water.
Robert H Probert
Robert H Probert Technical Services
Garner, North Carolina
June 14, 2013