Ted Mooney, P.E. RET
- Pine Beach, NJ
The authoritative public forum
for Metal Finishing since 1989
-----
Electroplated gold turns red
Q. I have met this problem for a long time, and it confused me. There are too many factors to cause this reddish phenomenon.
And we changed pH to low limit 5.5 and the content to the upper limit 10 g/L.
It seems we got some improvement but we still cannot solve it completely.
We analyzed the contents of Ni and copper and Ni=144 ppm, Cu=30 ppm, but we have not any method to decrease these contents only go on plating with above parameters to lower the effect of Ni and Copper.
- Donguan, China
October 30, 2024
⇩ Related postings, oldest first ⇩
Q. We are using Printed Wired Board with a selective electroplated gold realized with a deposition of gold over nickel over copper.
The Gold bath contain 99.7% pure gold, 0.25% Cobal (to have 180hv hard gold).
Actually we have a problem because the gold surface turn red if in contact with environment (originally we receive them as clean yellow). The boards are finished with olse OSP (Organic surface Preservative) studied not to remain on gold. Any idea about what kind of pollution can come from the plating process or PWB manufacturing final stages that can give this effect?
Alessio Agrestielectronics manufacturing - Bologna, Italy
2004
by Reid & Goldie
(hard to find & expensive; if you
see a copy cheap, act fast)
on eBay or
AbeBooks
or Amazon
(affil links)
|
A. This could also be a problem of surface topography instead of contamination. The reflectivity and wave length of the incident rays change by the surface condition. Check if the red color remains after a soft and bright mechanical polishing. Guillermo MarrufoMonterrey, NL, Mexico A. A good place to look is at the Nickel plating. If it is porous the copper migrates into the Gold. A chemical analysis of the Gold surface can determine this. Tom Gallant- Long Beach, California, USA |
by C W Zanariah Ngah
on eBay or
AbeBooks
or Amazon
(affil links)
Q. Dear Ladies and Gentlemen,
I have a plating work shop in biggest jewellery manufacturers' complex in Istanbul-Turkey.
My problem is when we electro-plate 23k gold on 18k rings, it sometimes turns red-ish after a while. l will be very thankful if anyone can solve my problem.
- Turkey
October 15, 2012
A. Hi Mehmet,
Gold deposit turning reddish could be due to:
1. Gold porosity leading to corrosion.
2. Poor final water rinse after gold plating.
3. Gold plating bath is contaminated with metallic impurities, such as copper or iron, which co-deposit with gold during electroplating.
Regards,
David
David Shiu
- Singapore
A. Hi,
This can be because of many things but usually is due to low gold content in the bath, poor water rinse. Implement final hot water rinse and, if possible, anti-tarnish.
- Mumbai, India
Q, A, or Comment on THIS thread -or- Start a NEW Thread