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Streaking problems in anodizing extrusions

Q. (6061-T6 material) My company designs and manufactures powered surgical hand-pieces. The housings for these hand-pieces are often machined from extruded aluminum shapes. We are struggling with getting to the root cause of a "streaking" problem that the anodize process brings out. The parts are machined and the remaining extruded surfaces are buffed, polished and glass beaded. When they leave the plant, they look very uniform cosmetically. After anodize, which is a type II clear coat, they have axial (along the axis of the extrusion) streaks in the part and we loose very expensive parts at the last operation. Our anodizer says that the etching is brings the lines out, but they cannot offer any solution. Does anyone have any ideas about what this may be?

Thanks for any help.

Roger McPherson
- Santa Ana, California, USA
2003

Q. Dear All,

Recently we have started Anodizing on pre fabricated Aluminium profiles and are facing the problem of caustic stains. These are not going even after doing proper desmutting.

Arun Nath
- Bangalore,Karnataka, India
March 29, 2012

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Q. We purchase and machine 6061-T6 extruded bar in 1.25" diameter. The finished product is Type II anodized and has a high requirement for cosmetics (color match, consistency, etch, etc.). Recently we've come across (for a second time) lots of aluminum that have what look like water spots in them. This is best described as a spot that has a slightly different reflectivity. Our guess is that it is material that wasn't alloyed properly but we're not intimately familiar with the extrusion/ingot process.

These spots are noticeable before anodizing and very noticeable afterwards. This may yield thousands upon thousands of dollars in scrap.

What is causing these material flaws? How can we avoid them? Should we pursue the material supplier?

Rob F
- Atlanta, Georgia
April 24, 2013

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Q. We are having problems with extruded 6063 T6 aluminum tubes for which we specified and purchased custom sized, extruding dies. Is there anything that can be done with the extruder to reduce streaks and spots in our extruded metal after anodizing? We are machining 1.5 mm off the extruded surface presently; would we get better results machining off a greater amount? Aside from specifying AQ material and temper, is there anything we should require of our extruder in way of extrusion specifications that would reduce the streaks and spots? Thanks for any advice regarding.

Scott Thompson
- Broomfield, Colorado
March 5, 2014

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Vertical streaks with hard anodizing after coloring

July 23, 2018

Q. Hello
The problem is manifested when solid anodizing and coloring in black alloys 7xxx, 6xxxx series. When anodizing alloy 2024, there is no problem.
The problem lies in the vertical stains that can be seen in the photos. These streaks are visible after the caustic etching step and washing on a dark film that is formed during etching. After the clarification stage in the nitric acid solution, the part becomes light and no streaks are observed. After the hard anodized sulphate, the film is uniform and no irregularities or streaks are seen.

Flows occur after the stage of staining and washing.
The caustic etching solution was changed. The nitric acid solution for clarification was changed. Washing was changed. The problem did not go away.
For some reason, the temperature of the environment has increased in the industry. Could this be the cause of this problem? Has anyone encountered such a problem?
In the morning, with the first cycle of anodizing, there were no issues. Parts were perfectly black. Temperature of 24 °C (75 °F). Issues with vertical stains begin during second cycle, when the temperature was 34°C (93 °F).
Parts on the suspension are placed in 3 rows, 6 pieces per row. Top row has the most noticeable stains, middle tier slightly noticeable stains, and the lower row has no defects at all.
Parts between containers are transferred manually, which takes 2-3 seconds.

I will be very grateful for the help in this matter. Thank you.

General view of the galvanic holder:

Detail view from the top row:

View from above detail top row:   

Bottom detail view top row:   

Detail view from middle row:

Bottom detail view middle row:

Detail view from lower row:



Bottom detail view lower row:

Photo details that are anodized one row:      

Oleh Hurenko
Technologist - Ukraine Kyiv

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July 26, 2018 A. Because the top row is the worse and the bottom row is OK, and because tremendous gassing is developed from the inside of the tubes and this gas is funneled toward the center, then the hydrogen gas evolution is scrubbing away the solution and current form the top row. Re-rack so that the gas evolution will not scrub solution away from the parts above. Robert H Probert Robert H Probert Technical Services Garner, North Carolina A. Hello Mr. Hurenko, That's awfully warm for anodizing! You should really be under 72 °F for regular anodize, and much cooler still for hard anodize. Are you running a chiller and mixing your tanks briskly during the processing? The first thing to do is get your temperature under control. I'm seeing a couple different types of marks on parts on the same rack- dots and smears- and you may have multiple things going on. I'd also think about your racking. Good stiff rack fingers, appropriate number of contact points for the surface area of the part, correct rack geometry for part geometry, tight bolts on the racks, and a tight connection between racks and flight bars. My view from here is if you optimize tank temperature and mixing, and then look at whether your racks are able to carry current adequately, you will see a huge improvement. It would be helpful to see the racking orientation of the parts in the lower pictures- coming off the holes, the staining does look like bleed out. You say you are using a nitric step between anodize and dye? That does help a lot. But a really vigorous spray rinse as the parts are coming out of each bath is still important. Start first off looking at your soap. Is there oil or wax on the surface when the agitation is turned off and the tank allowed to rest? The best time to chevk is first thing in the morning before startup. Some of the marks look like soap stains. I've seen this happen when we run heavy throughput of extrusions that had a waxy substance on them when they came in. It was very difficult to get a good water break (clean sheet of water, no droplets) after rinsing. That will certainly affect the ability to etch evenly and would account for the marks that are most randomly distributed with no obvious correlation to holes or rack points. Rachel Mackintosh lab rat - Greenfield, Vermont July 27, 2018

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September 2, 2018

Q. Rachel Mackintosh and Robert H Probert thank you for your answers. I apologize for the delay in the reply, was on a long trip. We lowered the temperature in the room by air conditioners. Now the room is 24 °C. Rachel Mackintosh temperature of electrolyte is -9 °C, in the process of anodizing there is a very aggressive circulation of electrolyte.
We build up an oxide layer 55-60 microns. Once again, there are no problems with such alloys as 2024. The problem occurs only with mullions 7075, 6063, 6082. The shape of the streaks corresponds to spills after alkaline etching of aluminum. The photo is circled in red. The time of transfer from the alkaline bath to the washing tank is a few seconds. the concentration of caustic soda in the cleaner is 200^⁵⁰ grams per liter.
I believe that these flows occur either after alkaline etching, or after anodizing, when transferred from the anodizing bath to the washing bath.
For some reason it seems to me that the flow data is exactly the effect of an alkaline solution, indicated in the photo.

Help please solve this problem. It is possible to use some impurities in the alkaline bath. It is possible to use an alternative to caustic soda ⇦liquid caustic soda in bulk on Amazon [affil link] . Perhaps someone faced such a problem?
I am very grateful for the answers.

Oleh Hurenko [returning]
AFT Hard Anodized - kiev Ukraine