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ted_yosem
Sound technical content, curated with aloha by
Ted Mooney, P.E. RET
Pine Beach, NJ
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Need a chemical-resistant black coating for steel or aluminum




Q. I need a chemical-resistant, wear-resistant black coating for aluminum or steel. This is for an optical read head in an automatic urinalysis machine. Black Anodize is bleached out by the urine/reagent chemicals, Titanium Aluminum Nitride and Titanium Carbonitride on steel are attacked by the urine/reagents or by household bleach (a 10% bleach solution is used for cleaning). We are using black Delrin (which is very gradually bleached by the urine/reagents) but it is difficult to hold the required tolerances in this material - we would rather use metal. The coating must be black and anti-reflective for optical reasons.

John W. Harrison
diagnostics - Tarrytown, New York
2003


A. If there are no halogens present (no problem with hypochlorite), a wild guess would be "Black Chromium" over dull sulfamate nickel. Chromium vendors are listed on finishing.com and you might want to talk with one of their research people. There is not much Black Chrome done in job shops because the demand is low but I think it might work for you.

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
probertbanner
2003


Black electroless nickel may work.

Todd Osmolski
- Charlotte, North Carolina, USA
2003



Q. I thought that Black Chromium (and Black Nickel) were dyed coatings like Black Anodize. If they are, I would think that they would be subject to the same bleaching as Black Anodize.

John W. Harrison [returning]
diagnostics - Tarrytown, New York
2003


A. There is no dye. They are electrodeposits that have been "poisoned" with other material and produce a very thin black deposit. Black nickel is nice, but rather soft and when it is scratched or abraded, it has a normal sort of bright nickel look. Black chrome would probably work better, tho there are not many job shops that do it.

James Watts
- Navarre, Florida
2003



A. Black Chromium Electroplating is NOT a dye !

robert probert
Robert H Probert
Robert H Probert Technical Services
supporting advertiser
Garner, North Carolina
probertbanner
2003



My company has supplied many firms in the optical and medical industries with black "optical" coatings including black nickel, black chrome and more recently electrolytically colored black anodize (no organic dyes to bleach). Black chrome with an electroless nickel underplate offers outstanding corrosion in many environs, however, yours is indeed unique.

milt stevenson jr.
Milt Stevenson, Jr.
Syracuse, New York
2003



2003

We have discussed the conditions of your application with our engineers and they suggest that black titanium will fit your needs and will never be bleached.

anna_berkovich
Anna Berkovich
Russamer Lab
supporting advertiser
Pittsburgh, Pennsylvania
russamer labs banner



ASM Metal Handbook
9th Edition, Vol. 5

"Surface Cleaning, Finishing & Coating"
asm_vol5old
on AbeBooks

or eBay or

Amazon

(affil links)

You need multilayered interference black mirror.
It consist of SiO2, Cr,SiO2,Cr,SiO2,Cr,SiO2 layers.
Each layer of Cr have transmission in vis 30-40%.
Each layer of SiO2 need be 1/4 thick for L (wave-length) 550nm.
It will be most chemical resistant coat.

Afanasev Konstantin
- Moscow, Russia
2005


Ceramic coating in matte black would be just fine for this application. It resists a 10 year controlled environment of 50/50 salt spray is almost completely chemical resistant and has wear resistance. This might be why the military coats most of their weapons in it. :)

Ryan Jones
- gautier Mississippi usa
February 11, 2011




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