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Letter 30001
Passivating Laser Marked 15-5 PH
Stainless Steel Parts
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We are manufacturing components made from 15-5 PH Stainless steel
for use in some of our aerospace assemblies. They require laser
marking and passivating. These parts cannot be submerged in a liquid
solution thus require passivating with a cotton or foam swab over the
markings. A company has created a liquid solution for us made from
water, potassium dichromate, and phosphoric acid. Not sure if this is
a viable solution or if there is a more effective process.
Does anyone have any information on passivating 15-5 PH in terms
of surface preparation and passivating the laser marked area?
Thanks,
Gary
Gary P 
Manufacturing Engineer (Aerospace engineering) - Wallingford, CT, USA
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I would look at two other approaches. Check with
Stellar Solutions, who
advertises here, possibly their citric based gel would be a more
practical solution to the problem. Another approach would be to talk
to the brush plating companies. At least one has a brush
electropolish which looks like it would be a good way.
James Watts
- FL
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Thanks for your input James, I will look them up.
Gary
- Wallingford
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Thanks a lot for the information.
Gary
- Wallingford
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Gary, why the heck would these require passivation? The way to do
assemblies, as you know, is to passivate the piece parts before you
assemble. Unless there's machining on these parts, through which
stray iron particles can get onto the surface of the 15-5, then the
original passivation is still good.
When we have to machine assemblies, we use carbide tooling or
grinding wheels dedicated to stainless steels, or some other such
controls to make sure we don't need to passivate again. Mere laser
marking will NOT affect the surface such that it'll require
passivation again.
Does your company have evidence that laser marking WILL affect
15-5 corrosion resistance? I've never seen such, and we've been laser
marking for decades...

Lee Gearhart
- East Aurora, NY
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Lee, thank you for your information. Before I started working
here, these laser marked parts were sent out for corrosion testing.
I'm told the laser marking did corrode, (without passivation over the
marking). I think I will run some tests myself. Anyway, the parts are
passivated after all machining, except for laser marking due to lot
control. I need to rub a passivating solution over the laser marking.
Your saying the laser marking has no effect on the original
passivated surface, and does not require re-passivating? Does it
matter how deep the laser marking is?
Thank you
Gary P [last name deleted for privacy dsue to age of
posting]
- CT
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Depending on the type and power of the laser you will normally
destroy the properties of the steel due to the high heat of the laser
etch. This is a major problem in the surgical and orthopedic
industries which has been resolved with the products mentioned above.
Many of these assemblies must be laser etched AFTER assembly, and
then the laser mark will rust in autoclaving or other disinfecting
processes, or in corrosive atmospheres. The weakest part of the
device for corrosion will be the laser etch. This is why they use a
paste on the laser etch area after assembly, but it must be a product
that passivates the etch without totally removing the desired black
color. Let us know if we can help.
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